Journal
ORGANIC LETTERS
Volume 16, Issue 3, Pages 684-687Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol403343s
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Funding
- 973 Program [2013CB933800, 2013CB834505]
- National Natural Science Foundation of China [21072202, 21222210, 91027041]
- Chinese Academy of Sciences
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A McMurry coupling reaction was used for the efficient synthesis of a bis(m-phenylene)-32-crown-10 based cryptand Z-3 with high yield. This photoresponsive cryptand formed host guest complexes with paraquat derivative 4 and 2,7-diazapyrenium derivative S. Z-3, and E-3 exhibited similar binding affinity to the small guest 4, while dramatic changes were observed in the binding affinity to the large guest 5.
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