Journal
ORGANIC LETTERS
Volume 16, Issue 6, Pages 1570-1573Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol5000988
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Funding
- National Natural Science Foundation of China [21172143, 21172145, 21372152, 21232004]
- Nippon Chemical Industrial Co., Ltd.
- Shanghai Jiao Tong University (SJTU)
- Instrumental Analysis Center of SJTU
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C-O bond cleavage of allylic alkyl ether was realized in a Pd-catalyzed hydrogen-bond-activated allylic alkylation using only alcohol solvents. This procedure does not require any additives and proceeds with high regioselectivity. The applicability of this transformation to a variety of functionalized allylic ether substrates was also investigated. Furthermore, this methodology can be easily extended to the asymmetric synthesis of enantiopure products (99% ee).
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