4.8 Article

Aerobic Oxynitration of Alkynes with tBuONO and TEMPO

Journal

ORGANIC LETTERS
Volume 16, Issue 24, Pages 6302-6305

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol503025n

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Funding

  1. DRDO, India [ARMREB/HEM/2014/159]
  2. CSIR
  3. DST

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An efficient method for stereoselective nitroaminoxylation of alkyne has been reported. The reaction enjoys a broad substrate scope, good functional group tolerance, and high yields. Synthetically useful a-nitroketones can be accessed through these products in a single step.

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