Journal
ORGANIC LETTERS
Volume 16, Issue 16, Pages 4118-4121Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol501815e
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Funding
- National Natural Science Foundation of China [21325209]
- Shanghai Municipal Committee of Science and Technology [14XD1404400]
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An efficient method for the preparation of highly optically active 3-allenyl- and 3-vinyl-4-aminochromanes by In-mediated intramolecular cyclization has been developed. The synthetic utilities of the approach were demonstrated by the construction of various chiral polycyclic heterocycles, especially the interesting spiroheterocyclic compound 9 and steroid analogue 10.
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