Journal
ORGANIC LETTERS
Volume 16, Issue 11, Pages 3082-3085Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol501183z
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Funding
- National Natural Science Foundation of China [21272183, 21002077]
- Fund of the Rising Stars of Shanxi Province [2012KJXX-26]
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A novel ruthenium-catalyzed cyclization of ketoxime carboxylates with N,N-dimethylformamide (DMF) for the synthesis of tetrasubstituted symmetrical pyridines has been developed. A methyl carbon on DMF performed as a source of a one carbon synthon. And NaHSO3 plays a role in the reaction.
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