Journal
ORGANIC LETTERS
Volume 16, Issue 15, Pages 3912-3915Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol501648a
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Funding
- Chinese Academy of Sciences
- National Natural Science Foundation of China [21222203, 21172226, 21133011]
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An asymmetric hydrogenation of sterically hindered beta,beta-disubstituted enones has been well-established by using a ruthenium complex composed of an achiral diphosphane and a chiral diamine as catalyst, wherein the carbonyl group was selectively hydrogenated to give a wide range of chiral allylic alcohols with high levels of enantioselectivity and complete chemoselectivity.
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