Journal
ORGANIC LETTERS
Volume 16, Issue 4, Pages 1052-1055Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol4035403
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Funding
- National Science Foundation [DMR-1104650]
- Division Of Materials Research
- Direct For Mathematical & Physical Scien [1104650] Funding Source: National Science Foundation
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A head-to-head photodimerization of a beta-substituted thiophene stacked face-to-face in the solid state using a ditopic hydrogen-bond-donor template is reported. The face-to-face stacking is attributed to contributions of intertemplate forces, which contrasts an assembly wherein the same thiophenes stack edge-to-face yet maintain a discrete hydrogen-bonded structure.
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