Journal
ORGANIC LETTERS
Volume 16, Issue 22, Pages 6036-6039Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol5031348
Keywords
-
Categories
Funding
- National Natural Science Foundation of China [21172017, 21372025, 21402005]
- National Basic Research Program of China [2013CB328905]
- start-up fund from the Public Hatching Platform for Recruited Talents of Beijing University of Chemical Technology
Ask authors/readers for more resources
A novel transition-metal-free, sulfur mediated allylic C-H alkylation reaction through a one-pot procedure involving an ene-like step between simple olefins and activated sulfoxides to generate allylic sulfonium intermediates, and a subsequent [2,3]-sigmatropic rearrangement step under basic conditions to give allylic C-H alkylation products, has been developed. This method is applicable to tri- and disubstituted olefin substrates in both inter- and intramolecular fashions.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available