Journal
ORGANIC LETTERS
Volume 16, Issue 3, Pages 1000-1003Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol403741m
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Funding
- National Natural Science Foundation of China [21302088, 21302087]
- Shenzhen special funds for the development of biomedicine, Internet, new energy, and new material industries [JCYJ20130401144532131, JCYJ20130401144532137]
- South University of Science and Technology of China (Talent Development Starting Fund from Shenzhen Government)
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A novel domino copper-catalyzed trifluoromethylated Meyer-Schuster rearrangement reaction with Togni's reagent was developed, leading to a-trifluormethyl (CF3) enone products with moderate to good yields. Furthermore, alpha-CF3 enones can be transformed toward important trifluoromethyl heterocyclic motifs in a one-pot version.
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