4.8 Article

NHC-AuCl/Selectfluor: A Highly Efficient Catalytic System for Carbene-Transfer Reactions

Journal

ORGANIC LETTERS
Volume 16, Issue 17, Pages 4472-4475

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol502018d

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The combination of NHC-gold complex and Selectfluor has been found to be a highly efficient catalyst system for carbene-transfer reactions, with a turnover number (TON) up to 990000 and a turnover frequency (TOF) up to 82500 h(-1).

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