4.8 Article

Rigid π-Extended Triptycenes via a Hexaketone Precursor

Journal

ORGANIC LETTERS
Volume 16, Issue 3, Pages 704-707

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol403383y

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Funding

  1. Fond der Chemischen Industrie (FCI)
  2. Deutsche Forschungsgemeinschaft (DFG)

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A high-yielding synthesis of a rigid hexaketone is presented that can be transformed into pi-extended D-3h-symmetric triptycene derivatives with high internal molecular free volumes (IMFVs). The products show excellent photophysical properties combined with high specific surface areas.

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