Journal
ORGANIC LETTERS
Volume 16, Issue 21, Pages 5624-5627Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol502685z
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Funding
- Naito Foundation
- Cooperative Research Program of Medical Mycology Research Center
- Chiba University
- Grants-in-Aid for Scientific Research [25460115, 25670043] Funding Source: KAKEN
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Four new polyketides, amphidinins CF (14), have been isolated from the culture broth of symbiotic dinoflagellate Amphidinium sp. The analysis of their spectral data revealed that amphidinins CF (14) were 4,5-seco-analogues of amphidinolide Q (5). The absolute configurations of the new compounds were elucidated by the combination of J-based configuration analysis, modified Moshers method, and chemical derivatization. Amphidinins D (2) and F (4) are the first glycosides related to amphidinolides. Amphidinins CF (14) showed antimicrobial activity against bacteria and/or fungi.
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