Journal
ORGANIC LETTERS
Volume 17, Issue 2, Pages 176-179Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol503455r
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Funding
- NSFC [91213302, 21272102, 81473095, 21432003]
- National S&T Major Project of China [2012ZX09504001-003]
- Program for Changjiang Scholars and Innovative Research Team in University [PCSIRT: IRT1137]
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An asymmetric formal [3 + 2]-cycloaddition between meso-aziridines and C3-alkylindoles mediated by an in situ generated magnesium catalyst was developed for asymmetric construction of pyrroloindolines. A variety of pyrroloindolines could be obtained by employing commercial available ligands with the assistance of an easily prepared achiral ligand.
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