Journal
ORGANIC LETTERS
Volume 16, Issue 16, Pages 4312-4315Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol502043j
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Funding
- National Science Foundation [CHE-1152488]
- National Institutes of Health [NIGMS 104349]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1152488] Funding Source: National Science Foundation
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A regioselective arylation of 1,1,3-triaryl-2-azaallyl anions with aryl chlorides is described. The palladium-NIXANTPHOS-based catalyst affords diarylmethylamine derivatives in good yield and without product isomerization. A gram scale sequential one-pot ketimine synthesis/arylation protocol was also developed.
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