Journal
ORGANIC LETTERS
Volume 16, Issue 14, Pages 3768-3771Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol501638x
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Funding
- National Science Foundation of China [21272087, 21232003]
- National Basic Research Program of China [2011CB808603]
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An unprecedented three-component coupling reaction of arynes, alpha-bromo carbonyl compounds, and DMSO triggered by insertion of arynes into the S=O bond of DMSO has been developed. The reaction can generate a wide range of multisubstituted aryl methyl thioethers in good yields, wherein DMSO serves as both methylthiolation reagent and oxygen source.
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