Journal
ORGANIC LETTERS
Volume 16, Issue 6, Pages 1680-1683Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol5003412
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- TUBITAK
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An enhanced chemiluminescence signal is obtained when electronically triggered dioxetane cleavage is initiated by fluoride-mediated deprotection of the silyl-protecting group, followed by self-immolation via 1,4-quinone-methide rearrangement. The reaction takes place even when the probe is trapped within a PMMA layer on top of a glass plate. In that arrangement, fluoride in aqueous solutions can be detected selectively at low micromolar concentrations.
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