Journal
ORGANIC LETTERS
Volume 16, Issue 16, Pages 4212-4215Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol5019135
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Funding
- Funding Program for Next Generation World-Leading Researchers from JSPS
- MEXT [25105720]
- KAKENHI from MEXT [25708005]
- World Premier International Research Center (WPI) Initiative, Japan
- National Science Foundation of China [21222510]
- Grants-in-Aid for Scientific Research [25708005] Funding Source: KAKEN
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A ligand-controlled branch-selective allylic C-H carboxylation through Pd catalysis is described. The developed catalytic system, which consists of Pd(OAc)(2), sulfoxide oxazoline (sox) as a ligand and benzoquinone as an oxidant, couples terminal alkenes and carboxylic acids to furnish the corresponding branched allylic esters with high regioselectivity.
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