Journal
ORGANIC LETTERS
Volume 16, Issue 16, Pages 4232-4235Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol501933h
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Funding
- National Natural Science Foundation of China [21202207, J1103305]
- Research Fund for Guangzhou Peal River New Star of Science and Technology [2013J2200017]
- Fundamental Research Funds for the Central Universities
- Program for Changjiang Scholars and Innovative Research Team in University of China [IRT1298]
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The first visible-light induced cross-dehydrogenative coupling between tertiary amines and diazo compounds is described. The reaction proceeds smoothly under mild and metal-free conditions by using air or O-2 as the oxidant, affording various beta-amino-alpha-diazo adducts in moderate to good yields with broad substrate scopes. The resulting products were successfully employed for the synthesis of 4- or 5-ester N-aryl-2,3-dihydrobenzo[d]azepines with high regioselectivity simply switched by the selection of the transition metal catalysts.
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