Journal
ORGANIC LETTERS
Volume 16, Issue 15, Pages 3888-3891Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol5015569
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Funding
- Ministry of Education, Culture, Sports, Science, and Technology (MEXT) of Japan [18406002, 25293025, 2586501]
- Uehara Memorial Foundation
- Grants-in-Aid for Scientific Research [25860501, 26660093, 25410044, 26860067, 26305005, 25293025] Funding Source: KAKEN
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Five new manzamine alkaloids, acanthomanzamines A-E, were isolated from the marine sponge Acanthostrongylophora ingens. Acanthomanzamines A and B are the first examples, containing a tetrahydroisoquinoline instead of a beta-carboline in manzamine-related alkaloids. Acanthomanzamine C contains a hexahydrocyclopenta[b]-pyrrol-4(2H)-one ring that may be converted from an eight-membered ring in manzamine A. Acanthomanzamines D and E have an additional oxazolidine and 2-methyloxazolidine rings, respectively, which fuse to the manzamine skeleton.
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