Journal
ORGANIC LETTERS
Volume 16, Issue 10, Pages 2634-2637Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol500800z
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Funding
- Deutsche Forschungsgemeinschaft [SFB 749]
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A short total synthesis, guided by biosynthetic considerations, of racemic merochlorin B is presented. The formation of its isomer, merochlorin A, was not observed under the conditions. Key steps include a directed ortho-metalation (DoM), a selective demethylation, an ortho-allylation, and an oxidative [3 + 2] -cycloaddition mediated by an iodine(III) reagent.
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