4.8 Article

2-Iodoisatogens: Versatile Intermediates for the Synthesis of Nitrogen Heterocycles

Journal

ORGANIC LETTERS
Volume 17, Issue 2, Pages 390-392

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol503487f

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Funding

  1. GlaxoSmithKline
  2. EPSRC
  3. Engineering and Physical Sciences Research Council [1614886] Funding Source: researchfish

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A Cu-promoted cyclization of 2-nitrophenyl iodoacetylenes provides a direct route to a range of 2-iodoisatogens. These compounds represent useful intermediates for the late-stage elaboration of the C-I bond to furnish isatins and a range of alternative heterocyclic products.

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