Journal
ORGANIC LETTERS
Volume 16, Issue 19, Pages 5132-5135Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol502490t
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- CSIR-New Delhi
- CSIR-OSDD for the Tata-CSIR-OSDD fellowship [tcof-6]
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An operationally simple multicomponent coupling involving in situ generated arynes from 2 (trimethylsilyl)aryl triflates, phosphines, and various acyclic and cyclic activated carbonyl compounds has been developed. The reaction proceeds via a formal [3 + 2] cycloaddition mode giving access to differently substituted (spiro)benzoxaphosphole derivatives in moderate to good yields Mild reaction conditions. a broad scope. and the possibility of varying all the three-components are the notable features of the present reaction.
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