4.8 Article

Cyano-Substituted Perylene Diimides with Linearly Correlated LUMO Levels

Journal

ORGANIC LETTERS
Volume 16, Issue 2, Pages 394-397

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol403250r

Keywords

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Funding

  1. National Natural Science Foundation of China [21225209, 91027043, 91233207]
  2. 973 Program [2011CB932301, 2013CB933500]
  3. NSFC-DFG [TRR61]
  4. Chinese Academy of Sciences

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A series of nonbay region cyano-substituted tetrachloroperylene diimides with tunable LUMO energy levels from -4.21 to -4.64 eV were developed. The excellent linear correlation between LUMO energy levels and the number of cyano groups indicated that the LUMO energy levels could be lowered effectively and predictably by incorporating cyano groups.

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