Journal
ORGANIC LETTERS
Volume 16, Issue 16, Pages 4280-4283Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol5020015
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Funding
- National Science Foundation [CHE-0848121, CHE-01162222]
- National Science Foundation Graduate Research Fellowship [DGE-1342536]
- NYU Department of Chemistry
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The cobalt-catalyzed peroxidation of silyl enol ethers with molecular oxygen and triethylsilane provided silyl monoperoxyketals in 54%-96% yield. These compounds serve as precursors to peroxycarbenium ions, which undergo annulations to provide 1,2-dioxolanes.
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