Journal
ORGANIC LETTERS
Volume 17, Issue 1, Pages 42-45Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol503210q
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Funding
- National Natural Science Foundation of China [21272166]
- Major Basic Research Project of the Natural Science Foundation of the Jiangsu Higher Education Institutions [13KJA150004]
- Program for New Century Excellent Talents in University [NCET-12-0743]
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
- Scientific and Technologic Infrastructure of Suzhou [SZS201207]
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A formal thio [3 + 3]-cyclization catalyzed by a DPEN-derived chiral thiourea has been reported for the construction of optically active thiopyrano-indole annulated heterocyclic compounds in high yields with excellent enantioselectivities. The high reactivity between indoline-2-thione (keto-S) and 2-benzylidenemalononitrile has also been supported by density functional theory (DFT) calculations.
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