Journal
ORGANIC LETTERS
Volume 16, Issue 13, Pages 3468-3471Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol501389k
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Palladium(0)-catalyzed conditions for the alpha-arylation of sultams with aryl and heteroaryl iodides have been developed. Arylation of 3-substituted 1,3-propanesultams gave rise to high yields and high diastereomeric ratios, leading to the thermodynamically favored cis product. The arylation was broadly applicable to various electron-rich and electron-poor (hetero)aromatic iodides.
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