Journal
ORGANIC LETTERS
Volume 16, Issue 14, Pages 3620-3623Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol5013907
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Funding
- National Science Foundation [CHE-1150606]
- Robert A. Welch Foundation [A-1700]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1150606] Funding Source: National Science Foundation
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An iron-catalyzed formal hydroamination of alkenes has been developed. It features O-benzoyl-N,N-dialkylhydroxylamines as the electrophilic nitrogen source and cyclopentylmagnesium bromide as the reducing agent for intermolecular hydroamination of styrene and derivatives with good yield and excellent Markovnikov regioselectivity. The reaction presumably proceeds through the iron-catalyzed hydrometalation of styrene followed by electrophilic amination with the electrophilic O-benzoylhydroxylamine.
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