Journal
ORGANIC LETTERS
Volume 16, Issue 5, Pages 1438-1441Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol5002297
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Funding
- Ministry of Science [MD-1151.2011.3]
- Russian Foundation for Basic Research [13-03-12074, 14-03-00293, 14-03-31253_mol_a, 14-03-31265_mol_a]
- Russian Academy of Sciences
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A new difluorinated reagent, [difluoro(trimethylsilyl)methyl]zinc bromide, bearing C-Zn and C-Si bonds is described. The reagent is conveniently prepared by cobalt-catalyzed halogen/zinc exchange. It can be coupled with two different C-electrophiles in a stepwise manner (with allylic halides for C-Zn bond and aldehydes for C-Si bond) affording products containing a difluoromethylene fragment.
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