Journal
ORGANIC LETTERS
Volume 16, Issue 3, Pages 784-787Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol403516s
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Funding
- Lund University
- Crafoord Foundation
- COST [CM 0804]
- Archimedes Foundation [3.2.0501.10-0004]
- Estonian Ministry of Education [SF0180073s08]
- Royal Physiographic Society
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A Diels-Alder reaction is used as a key step in a synthetic study toward communesin F, in order to simultaneously introduce both of the all-carbon quaternary stereocenters with complete control of relative stereochemistry. Further manipulations of the cycloadduct, toward the hexacyclic core-structure of communesin F, are also disclosed.
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