Journal
ORGANIC LETTERS
Volume 16, Issue 11, Pages 3102-3105Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol501211z
Keywords
-
Categories
Funding
- Natural Science Foundation of Zhejiang Province [R4110195]
- Science & Technology Department of Zhejiang Province [2013C24004]
Ask authors/readers for more resources
Thioperoxide (1) in combination with trimethylsilyl trifluoromethanesulfonate (TMSOTf) provides a powerful thiophilic promoter system, capable of activating different thioglycosides. Both armed and disarmed thioglycosides were activated effectively in the presence of different glycosyl acceptors, giving glycosidation products in high to excellent yields. A plausible activation pathway was also proposed and supported by isolating side-products trifluoromethylphenyl disulfide (CF3SSPh) and alkene (42).
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
