Journal
ORGANIC LETTERS
Volume 16, Issue 14, Pages 3688-3691Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol5014747
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Funding
- National Science Foundation of China [21272096]
- Fundamental Research Funds for the Central Universities [lzujbky-2014-58]
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An I2O5-promoted free-radical cascade trifluoromethylation/cyclization of a broad range of N-arylmethacrylamides and enynes with sodium trifluoromethanesulfinate in aqueous medium has been achieved. This strategy allows highly selective access to a variety of CF3-containing oxindoles and pyrrolidines. Electron spin resonance (ESR) studies indicate that atom-transfer processes are involved in this system.
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