Journal
ORGANIC LETTERS
Volume 16, Issue 9, Pages 2470-2473Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol500850d
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Funding
- National Natural Science Foundation of China [21102064]
- Natural Science Foundation of Department of Science & Technology of Gansu Province [1208RJYA030]
- Fundamental Research Funds for the Central Universities [Izujbky-2013-73]
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An alternative method to an iron-catalyzed radical oxidative cross-coupling reaction followed by 2-chloro-1,3-dithiane and aryl olefins for the synthesis of beta-chloro substituent 1,3-dithiane products is presented. The described method has the advantage of mildness of the reaction conditions and tolerates a variety of functional groups. Preliminary mechanistic studies have confirmed the first example of a coupling of 1,3-dithiane with unactivated alkenes that proceeds via an iron-catalyzed oxidative radical intermediate along the reaction pathway.
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