Journal
ORGANIC LETTERS
Volume 16, Issue 16, Pages 4272-4275Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol501997n
Keywords
-
Categories
Funding
- Nanyang Technological University
- Singapore Ministry of Education
- LKY PDF
- Ecole Polytechnique
- University of Strasbroug
Ask authors/readers for more resources
Radical perfluoroalkylation of alpha-(biaryl-2-yl)vinyl azides is capable of supplying polyfluoroalkyl aza-polycyclic aromatic hydrocarbons (aza-PAHs). Commercially available Me3SiRf (R-f = CF3, C2F5, and C3F7) are employed as the sources of perfluoroalkyl radicals upon oxidation with PhI(OAc)(2). The addition of perfluoroalkyl radicals to biarylvinyl azides generates the corresponding iminyl radicals, which subsequently cyclize with the intramolecular arene moiety, furnishing aza-PAH skeletons having polyfluoroalkyl (RfCH2) function.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available