Journal
ORGANIC LETTERS
Volume 16, Issue 12, Pages 3188-3191Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol501054c
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Funding
- National Key Project for Basic Research [2010CB126100]
- National Natural Science Foundation of China [21132003, 21121002, 21372131]
- Specialized Research Fund for the Doctoral Program of Higher Education [20130031110017]
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Copper-catalyzed intramolecular trifluoromethylation of N-benzylacrylamides coupled with dearomatization was achieved and used to regiospecifically construct a variety of trifluoromethylated 2-azaspiro[4.5]decanes bearing adjacent quaternary stereocenters under mild conditions in moderate to excellent yields.
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