Journal
ORGANIC LETTERS
Volume 16, Issue 11, Pages 3090-3093Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol5011888
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Funding
- JSPS [22380114]
- Yokohama City University [T2202, T2309, T2401]
- Grants-in-Aid for Scientific Research [22380114] Funding Source: KAKEN
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A new polyamine-modified indole derivative protoaculeine B (1) was isolated from Okinawan marine sponge Axinyssa aculeata. The structure of 1 was assigned on the basis of spectral data along with chemical transformations. Because the structure of 1 greatly inferred the N-terminal amino acid for highly modified peptide toxin aculeines, the probable structure for aculeine B was proposed on the basis of high-resolution mass spectral analysis.
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