Journal
ORGANIC LETTERS
Volume 16, Issue 10, Pages 2736-2739Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol501022d
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- JSPS
- Grants-in-Aid for Scientific Research [25860004] Funding Source: KAKEN
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A copper(II)-catalyzed intermolecular three-component oxyarylation of allenes using arylboronic acids as a carbon source and TEMPO as an oxygen source is described. The reaction proceeded under mild conditions with high regio- and stereo-selectivity and functional group tolerance. A plausible reaction mechanism is proposed, involving carbocupration of allenes, homolysis of the intervening allylcopper(II), and a radical TEMPO trap.
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