Journal
ORGANIC LETTERS
Volume 16, Issue 22, Pages 5940-5943Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol502968c
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- National Natural Science Foundation of China [21272190]
- PCSIRT in University
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A highly efficient Pt-catalyzed [3,3] sigmatropic rearrangement/cyclization cascade of N-propargylhydrazones is reported. The process provides expedient access to a variety of highly functionalized pyrazoles. The substrate has good substituted group compatibility, and the bioactive 3-CF3 pyrazoles could be synthesized easily with this method.
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