Journal
ORGANIC LETTERS
Volume 16, Issue 9, Pages 2438-2441Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol5008185
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Funding
- NSFC [21372105, 21032005, 21172097]
- PCSIRT [IRT1138]
- International S&T Cooperation Program of China [2013DFR70580]
- National Basic Research Program of China [2010CB833203]
- MOE of P.R. China
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Application of indolin-3-one derivatives in a cascade reaction for efficient assembly of complex molecules is a much less explored research area. It is demonstrated that structurally interesting polysubstituted piperidino[1,2-a]indoline compounds containing four contiguous stereocenters including one tetrasubstituted carbon center can be readily obtained with good yields (up to 94% yield) and excellent enantioselectivities (up to >99% ee) by employing indolin-3-one derivatives as substrates via bifunctional catalysis.
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