Journal
ORGANIC LETTERS
Volume 16, Issue 2, Pages 504-507Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol403391v
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Funding
- National Natural Science Foundation of China [21302088, 21302087]
- Shenzhen special funds for the development of biomedicine, Internet, new energy, and new material industries [JCYJ20130401144532131, JCYJ20130401144532137]
- South University of Science and Technology of China
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The first example of a metal-free direct carbotrifluoromethylation of alkenes using inexpensive TMSCF3 as the CF3 source is described. The methodology not only exhibits high chemoselectivity for this transformation but also expands the substrate scope that is difficult to access by known transition-metal-catalyzed methods.
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