4.8 Article

Palladium-Catalyzed Cascade Oxidation/sp2 C-H Acylation of Azoarenes with Aryl Methanes

Journal

ORGANIC LETTERS
Volume 15, Issue 21, Pages 5444-5447

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol402537t

Keywords

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Funding

  1. NSFC [21072063, 21272229]
  2. West Light Foundation of CAS [Y3C1011100]

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A Pd-catalyzed cascade oxidation/sp(2) C-H bond acylation of azoarenes was developed in which readily available aryl methanes were used as the in situ generated acyl sources. This reaction provides a convenient access to ortho-acyl azoarenes under mild conditions.

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