Journal
ORGANIC LETTERS
Volume 15, Issue 6, Pages 1334-1337Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol400274f
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- Department of Science and Technology, New Delhi
- Council of Scientific and Industrial Research, New Delhi
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The oxidative C-H amination of N ''-aryl-N'-tosyl/N'-methylsulfonylamidines and N,N'-bis(aryl)amidines has been accomplished using iodobenzene as a catalyst to furnish 1,2-disubstituted benzimidazoles in the presence of mCPBA as a terminal oxidant at room temperature. The reaction is general, and the target products can be obtained in moderate to high yields.
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