4.8 Article

Remarkable Catalytic Property of Nanoporous Gold on Activation of Diborons for Direct Diboration of Alkynes

Journal

ORGANIC LETTERS
Volume 15, Issue 22, Pages 5766-5769

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol4028013

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Funding

  1. Japan Society for Promotion of Science (JSPS) [23245020]
  2. World Premier International Research Center Initiative (WPI), MEXT, Japan
  3. China Scholarship Council (CSC)
  4. Grants-in-Aid for Scientific Research [23245020, 25286012, 24106702] Funding Source: KAKEN

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A novel catalytic property of nanoporous gold for activation of bis(pinacolato)diboron has been reported that allows the direct diboration of alkynes to proceed sufficiently in a heterogeneous process. The experimental results revealed that the nanoporous gold catalyst is able to cleave the B-B bond of bis(pinacolato)diboron without using any additives.

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