Journal
ORGANIC LETTERS
Volume 15, Issue 19, Pages 5102-5105Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol402472q
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Funding
- JSPS KAKENHI [24790026]
- Grants-in-Aid for Scientific Research [24790026] Funding Source: KAKEN
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The first total synthesis of (+)-gregatin E and a new total synthesis of (+)-gregatin B are described. Key features of our synthetic approach involve a palladium-catalyzed cyclization-methoxycarbonylation of optically active propargylic acetate and a Suzuki-Miyaura coupling or CuTC-mediated coupling reaction. The absolute configuration of (+)-gregatin E (5R,5'S) is proposed.
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