Journal
ORGANIC LETTERS
Volume 15, Issue 15, Pages 4034-4037Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol4019375
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- A*STAR, Singapore
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In the presence of a Cu(I)/NHC catalyst, the reactions of allylboronic pinacol esters with CO2 (1 atm) are highly regioselective, giving exclusively the more substituted beta,gamma-unsaturated carboxylic acids in most cases. A diverse array of substituted carboxylic acids can be prepared via this method, including compounds featuring all-carbon quaternary centers.
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