Journal
ORGANIC LETTERS
Volume 15, Issue 10, Pages 2566-2569Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol401095k
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Funding
- Tufts University
- Robert R. Dewald Summer Scholarship
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A method for the highly selective synthesis of 1,2-cis-alpha-linked glycosides that does not require the use of the specialized protecting group patterns normally employed to control diastereoselectivity is described. Thioglycoside acceptors can be used, permitting iterative oligosaccharide synthesis. The approach eliminates the need for lengthy syntheses of monosaccharides possessing highly specialized and unconventional protecting group patterns.
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