Journal
ORGANIC LETTERS
Volume 15, Issue 3, Pages 542-545Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol303363r
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Funding
- National Basic Research Program of China [2011CB808603]
- National Natural Science Foundation of China [21232003, 21202053]
- CCNU
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A formal [4 + 1]/[3 + 2] cycloaddition sequence of sulfur ylides and alkene-tethered nitroolefins has been developed. The use of (R)-binol-derived chiral sulfide leads to an asymmetric process that allows the construction of oxa- and aza-angular triquinanes In good to excellent diastereo- and enantioselectivities.
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