Journal
ORGANIC LETTERS
Volume 15, Issue 19, Pages 5134-5137Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol4025716
Keywords
-
Categories
Funding
- NIH [GM073836]
- Australian Research Council
Ask authors/readers for more resources
A mild Cu-catalyzed nucleophilic fluorination of unsymmetrical diaryliodonium salts with KF is described. This protocol preferentially fluorinates the smaller aromatic ligand on Iodine(III). The reaction exhibits a broad substrate scope and proceeds with high chemoselectivity and functional group tolerance. DFT calculations implicate a Cu-I/Cu-III catalytic cycle.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available