Journal
ORGANIC LETTERS
Volume 15, Issue 21, Pages 5520-5523Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol4026827
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Funding
- National Basic Research Program of China [2011CB935800]
- 863 program [2013AA092903]
- National Natural Science Foundation of China [21121091, 21102072]
- Natural Science Foundation of Jiangsu Province [BK2012012, BK20131266]
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A mechanistically new strategy has been described for the simple, practical, and environmentally friendly preparation of 6-(trifluoromethyl)phenanthridine derivatives using ionic isocyanide insertion from biphenyl isocyanide derivatives and Umemoto's reagent. These reactions were promoted only by inorganic base in good-to-excellent chemical yields without any external stoichiometric oxidants and radical initiators.
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