Journal
ORGANIC LETTERS
Volume 15, Issue 11, Pages 2664-2667Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol400946k
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Funding
- Specialized Research Fund for the Doctoral Program of Higher Education [20103201120006]
- NSFC [21102097]
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
- Soochow University
- Jiangsu Province Higher Education Graduate Student Research and Innovation Project [CXLX11_0067]
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Direct arylation of unactivated arenes or heteroarenes with aryl halides could be carried out in the presence of potassium tert-butoxide and dimethyl sulfoxide under visible-light irradiation. Ir(ppy)(3) was found to be an effective photoredox catalyst for this reaction. The reactions of aryl iodides occurred at room temperature. Elevated temperature was required for aryl bromides. Homolytic aromatic substitution was proposed to be the operative reaction pathway.
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