4.8 Article

Ruthenium-Catalyzed Regioselective C-H Alkenylation Directed by a Free Amino Group

Journal

ORGANIC LETTERS
Volume 15, Issue 15, Pages 3990-3993

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol401779h

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Funding

  1. MEXT
  2. JSPS
  3. JST, Japan
  4. Grants-in-Aid for Scientific Research [25105733, 25288048] Funding Source: KAKEN

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The ruthenium-catalyzed alkenylation reactions of 2-aminobiphenyls and cumylamine proceed smoothly to produce the corresponding regioselectively alkenylated products. These reactions involve a C-H bond cleavage directed by their free amino groups.

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